Modular diphosphine ligands based on bisphenol A backbones

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Abstract

A straightforward two-step synthesis is used to obtain new phosphorus-containing ligands based on readily available bisphenol A type backbones. Five diphosphine ligands have been prepared in good yields. An X-ray crystallographic study is presented for ligand 5. Preliminary results on rhodium-catalyzed hydroformylation exemplify the use of these ligands for homogeneous catalysis. © 2003 Elsevier Science Ltd. All rights reserved.

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Van Der Vlugt, J. I., Bonet, J. M., Mills, A. M., Spek, A. L., & Vogt, D. (2003). Modular diphosphine ligands based on bisphenol A backbones. Tetrahedron Letters, 44(23), 4389–4392. https://doi.org/10.1016/S0040-4039(03)00948-1

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