3-Ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes

  • Klimova E
  • Klimova T
  • Bakinovsky L
 et al. 
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Abstract

Dehydrobromination of isomeric 3-bromo-1-ferrocenyl-2-methylcyclopropanes afforded 3-ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes. These undergo smooth opening of the three-membered ring to give 1- and 2-ferrocenylbuta-1,3-dienes and 1- and 2-methyl-1H-cyclopentaferrocenes; with 1,3-diphenylisobenzofuran they give the classical Diels-Alder adducts. © 2005 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Cyclopropane
  • Cyclopropene
  • Ferrocene
  • Intramolecular transformations
  • Opening of the three-membered ring

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