3-Ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes

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Abstract

Dehydrobromination of isomeric 3-bromo-1-ferrocenyl-2-methylcyclopropanes afforded 3-ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes. These undergo smooth opening of the three-membered ring to give 1- and 2-ferrocenylbuta-1,3-dienes and 1- and 2-methyl-1H-cyclopentaferrocenes; with 1,3-diphenylisobenzofuran they give the classical Diels-Alder adducts. © 2005 Elsevier B.V. All rights reserved.

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Klimova, E. I., Klimova, T., Bakinovsky, L. V., & Martínez García, M. (2006). 3-Ferrocenyl-1-methyl- and 1-ferrocenyl-3-methylcyclopropenes. Journal of Organometallic Chemistry, 691(3), 507–513. https://doi.org/10.1016/j.jorganchem.2005.09.016

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