Cyanoalkyl complexes of transition metals III. Reactions of organometallic complexes of palladium and platinum with sodium dicyanomethanide

  • Yamamoto H
  • Suzuki K
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Abstract

Reactions of MI(CH3)(PPh3)2or MCl(CH2COR)(PPh3)2(M = Pd, Pt) with sodium dicyanomethanide in methanol gave novel metal complexes. Spectroscopic data suggest that these complexes contain either an iminoether chelate ring or a carbon-carbon chelate ring which was derived from CH(CN)2-. © 1974.

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Authors

  • Hisashi Yamamoto

  • Keinosuke Suzuki

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