Hot-atom incorporation of tritium atoms into fullerenes

  • Jiménez-Vázquez H
  • Cross R
  • Saunders M
 et al. 
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Abstract

We have used classical hot-atom chemistry to put tritium atoms inside fullerene molecules. The tritium is generated in a nuclear reactor with the reaction6Li(n,α)3H. The hot tritium atom slows down and can end up being thermalized inside a fullerene where it is trapped. The irradiated sample is dissolved, chromatographed, and counted in a scintillation counter, showing a small tritium activity. After some time, the sample is analyzed with a sensitive mass spectrometer, and3He was found on heating above 400°C, showing that the tritium had decayed leaving the3He trapped inside the fullerene. © 1994.

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Authors

  • H. A. Jiménez-Vázquez

  • R. J. Cross

  • M. Saunders

  • R. J. Poreda

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