A novel synthetic method for (R)- and (S)-muscones by enantioselective hydrogenation of (E)- and (Z)-3-methyl-2-cyclopentadecen-1-ones catalyzed by p-tolyl-BINAP-Ru(II) complexes

  • Yamamoto T
  • Ogura M
  • Kanisawa T
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Abstract

A novel and practical synthesis of (R)- and (S)-muscones by the asymmetric hydrogenation of (E)- and (Z)-3-methyl-2-cyclopentadecen-1-ones catalyzed by p-tolyl-BINAP-Ru(II) complexes has been achieved in nearly complete enantioselectivity. © 2002 Published by Elsevier Science Ltd.

Author-supplied keywords

  • (E)- and (Z)-3-methyl-2-cyclopentadecen-1-one
  • (R)- and (S)-muscone
  • Asymmetric hydrogenation
  • p-tolyl-BINAP-Ru(II)

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Authors

  • Takeshi Yamamoto

  • Miharu Ogura

  • Tsuneyoshi Kanisawa

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