Peculiarities of the non-radiative decay of a single vibronic level in polyatomic molecules

  • Nitzan A
  • Jortner J
  • Rentzepis P
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Abstract

Optical selection experiments in the first excited singlet state of the benzophenone molecule in solution confirm a theoretical prediction concerning the retardation of the electronic relaxation rate with increasing the excess vibrational energy in excited electronic states of a large molecule characterized by a small electronic energy gap. © 1971.

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