Reactivity of triosmium and triruthenium carbon radicals toward fluoro- and hexafluorobenzen

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Abstract

The radicals H3M3(CO)9(μ3-C·), generated by photolyzing a mixture of Re2(CO)10and H3M3(CO)9(η3-CBr) (M = Ru, Os), are found to add to C6F6and C6H5F. With C6F6the major products are the pentafluorophenyl derivatives H3M3(CO)9(μ3-CC6F5), whereas with C6H5F the major products are the phenyl derivatives H3M3(CO)9(ν3-CC6H5). © 1991.

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Hadj-Bagheri, N., Strickland, D. S., Wilson, S. R., & Shapley, J. R. (1991). Reactivity of triosmium and triruthenium carbon radicals toward fluoro- and hexafluorobenzen. Journal of Organometallic Chemistry, 410(2), 231–239. https://doi.org/10.1016/0022-328X(91)80008-8

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