Reactivity of triosmium and triruthenium carbon radicals toward fluoro- and hexafluorobenzen

  • Hadj-Bagheri N
  • Strickland D
  • Wilson S
 et al. 
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Abstract

The radicals H3M3(CO)9(μ3-C·), generated by photolyzing a mixture of Re2(CO)10and H3M3(CO)9(η3-CBr) (M = Ru, Os), are found to add to C6F6and C6H5F. With C6F6the major products are the pentafluorophenyl derivatives H3M3(CO)9(μ3-CC6F5), whereas with C6H5F the major products are the phenyl derivatives H3M3(CO)9(ν3-CC6H5). © 1991.

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Authors

  • N. Hadj-Bagheri

  • D. S. Strickland

  • S. R. Wilson

  • J. R. Shapley

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