Solution thermodynamics of phenols

11Citations
Citations of this article
4Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The temperature-dependent solubilities of several series of phenols in a 0.15 M sodium chloride solution have been measured. Experimentally determined heats of solution are compared with calculated values based on solubility principles. The solution process of all phenols is entropy-dominated and functional group contributions to the solubility are attributed mainly to their relative sizes and hydrophobicities. The correlation between experimental and calculated solubilities is excellent within a given series of phenols but not so good between different series. Correlations found between aqueous solubilities and partition coefficients of compounds can be explained in terms of the entropy change of the process in each case. © 1982.

Cite

CITATION STYLE

APA

Rogers, J. A. (1982). Solution thermodynamics of phenols. International Journal of Pharmaceutics, 10(2), 89–97. https://doi.org/10.1016/0378-5173(82)90088-6

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free