The syntheses, characterizations, X-ray crystal structures and properties of Cu(I) complexes of a bis-bidentate schiff base ligand

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Abstract

Bis-bidentate Schiff base ligand L and its two mononuclear complexes [CuL(CH3CN)2]ClO4(1) and [CuL(PPh3)2]ClO4(2) have been prepared and thoroughly characterized by elemental analyses, IR, UV-Vis, NMR spectroscopy and X-ray diffraction analysis. In both the complexes the metal ion auxiliaries adopt tetrahedral coordination environment. Their reactivity, electrochemical and photophysical behavior have been studied. Complex 1 shows reversible CuII/Icouple with potential 0.74 V versus Ag/AgCl in CH2Cl2. At room temperature L is weakly fluorescent in CH2Cl2, however in Cu(I) complexes 1 and 2 the emission in quenched. © 2009 Elsevier B.V. All rights reserved.

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Mukherjee, A., Chakrabarty, R., Ng, S. W., & Patra, G. K. (2010). The syntheses, characterizations, X-ray crystal structures and properties of Cu(I) complexes of a bis-bidentate schiff base ligand. Inorganica Chimica Acta, 363(8), 1707–1712. https://doi.org/10.1016/j.ica.2009.12.009

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