Synthesis of 1-phosphono-2-aza-1,3-dienes and their conversion into 1- vinyl-2-phosphonoaziridines

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Abstract

1-Phosphono-2-aza-1,3-dienes were formed by 1,4-dehydrochlorination of the corresponding N-(phosphonomethyl)-a-chloroimines, and reacted smoothly with diazomethane to give 1-vinyl-2-phosphonoaziridines.

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Stevens, C., Gallant, M., & De Kimpe, N. (1999). Synthesis of 1-phosphono-2-aza-1,3-dienes and their conversion into 1- vinyl-2-phosphonoaziridines. Tetrahedron Letters, 40(17), 3457–3460. https://doi.org/10.1016/S0040-4039(99)00422-0

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