Transition metal-saccharide chemistry: Synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes

  • Mukhopadhyay A
  • Karkamkar A
  • Kolehmainen E
 et al. 
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Abstract

Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, D-ribose and D-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO2moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed. Copyright (C) 1998 Elsevier Science Ltd.

Author-supplied keywords

  • Bridging saccharide units
  • Dimeric structure
  • Solution stability
  • Transition metal-saccharide chemistry
  • cis-Dioxomolybdenum saccharides

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Authors

  • Anindita Mukhopadhyay

  • Abhijeet Karkamkar

  • Erkki Kolehmainen

  • Chebrolu P. Rao

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