Transition metal-saccharide chemistry: Synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes

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Abstract

Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, D-ribose and D-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO2 moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed. Copyright (C) 1998 Elsevier Science Ltd.

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Mukhopadhyay, A., Karkamkar, A., Kolehmainen, E., & Rao, C. P. (1998). Transition metal-saccharide chemistry: Synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes. Carbohydrate Research, 311(3), 147–154. https://doi.org/10.1016/S0008-6215(98)00186-4

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