Unprecedented carbocyclization of 1,6-allenynes on addition of organoboronic acids under Pd-catalysis

  • Gupta A
  • Rhim C
  • Oh C
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Abstract

In contrast to the ene behavior of allenes in Pauson-Khand reactions and other cyclization reactions, 1,6-allenynes undergo unprecedented carbocyclization followed by regioselective addition of organoboronic acids in the presence of Pd(OAc)2and tri-t-butyl phosphine under mild reaction conditions. © 2005 Elsevier Ltd. All rights reserved.

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