Ages and composition of gas trapped in Allan Hills and Byrd core ice

  • Fireman E
  • Norris T
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Gas is extracted from large (6-31 kg) Antarctic ice samples to obtain sufficient CO2for14C measurements with small low-level proportional counters. The14C ages of Byrd core ice are in accord with glaciological estimates ranging from (2.2-1.1+1.4)×103yr at 271 m depth to more than 8 × 103yr at 1071 m depth. The CO2abundances in gas extracted from Byrd core ice range from 0.0216 to 0.051%, with below present-day atmosphere CO2abundances for ice from 1068 and 1469 m depths. The CO2abundance in gas from Allan Hills surface ice samples ranges between four and six times the atmospheric value and the CO2had a specific activity three times that of contemporary carbon. A possible explanation for the anomalously high specific activity is surface melting with the incorporation into CO2of14C produced by cosmic ray spallation of oxygen in ice. The CO2abundance in gas extracted from subsurface Allan Hills ice ranged from 0.030 to 0.065%, and the specific activities are below contemporary carbon, indicating ages greater than ∼5×103yr. The18O/16O ratio of oxygen in the trapped gas is the same as that of atmospheric oxygen and differs markedly from the18O/16O ratio in the ice. The O2, N2, and Ar abundances and isotopic compositions are similar to those in contemporary air, except for positive15N/14N ratios in a few samples. © 1982.

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  • E. L. Fireman

  • T. L. Norris

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