The structure of BaBiO3 at 25°C has been solved and refined with the use of neutron diffraction powder data. The valence situation is found to be BaBi3+1 2Bi5+1 2O3 rather than BaBi4+O3. The Bi3+ and Bi5+ cations take on an ordered arrangement and the resultant structure has monoclinic symmetry 12/m (a = 6.181 A ̊, b = 6.136 A ̊, c = 8.670 A ̊, β = 90.17°). This is the first example of an ordered perovskite in which the ordered cations are the same element, and also represents the first case of Bi3+ octahedrally coordinated to oxygen. The semiconducting properties of BaBiO3 are readily understood on the basis of the ordered structure. The structure becomes rhombohedral at about 130°C, and cubic in the region of 450°C. © 1976.
CITATION STYLE
Cox, D. E., & Sleight, A. W. (1976). Crystal structure of Ba2Bi3+Bi5+O6. Solid State Communications, 19(10), 969–973. https://doi.org/10.1016/0038-1098(76)90632-3
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