Dithiodiolate Ligands: Group 4 complexes and application in lactide polymerization

  • Sergeeva E
  • Kopilov J
  • Goldberg I
 et al. 
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Abstract

Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear octahedral group 4 complexes of the type [{OSSO}M(OR)(2)], which features C(2) symmetry and fluxional behavior, and were highly active in the ring-opening polymerization of rac- and L-lactide.

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Authors

  • Ekaterina Sergeeva

  • Jacob Kopilov

  • Israel Goldberg

  • Moshe Kol

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