The effects of both geometric (Pt-Pt bond distance) and electronic (Pt d-band vacancy) factors on the electrocatalytic activity for the oxygen reduction reaction (ORR) of carbon supported Pt and Pt-Co alloy catalysts were investigated by X-ray diffraction and X-ray absorption spectroscopies in conjunction with electrochemical measurements in proton exchange membrane (PEM) fuel cells. In the presence of cobalt, a decrease in the Pt-Pt bond distance and an increase in the metal particle size were observed. In PEM fuel cells the ORR activity on all the Pt-Co/C catalysts was higher than that on Pt/C. A poor fit between the ORR activity and the Pt-Pt bond distance was found. Conversely, the ORR activity presented a linear relationship with the integrated intensity of the Pt L3 edge at 1.1 V, related to the Pt d-band vacancy. This is because this parameter takes into account both alloying (Pt-Pt bond distance) and particle size effects. © 2005 International Association for Hydrogen Energy. All rights reserved.
CITATION STYLE
Antolini, E., Salgado, J. R. C., Giz, M. J., & Gonzalez, E. R. (2005). Effects of geometric and electronic factors on ORR activity of carbon supported Pt-Co electrocatalysts in PEM fuel cells. International Journal of Hydrogen Energy, 30(11), 1213–1220. https://doi.org/10.1016/j.ijhydene.2005.05.001
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