Enhancement of ionic conductivity of composite membranes for all-solid-state lithium rechargeable batteries incorporating tetragonal Li<inf>7</inf>La<inf>3</inf>Zr<inf>2</inf>O<inf>12</inf> into a polyethylene oxide matrix

  • Choi J
  • Lee C
  • Yu J
 et al. 
  • 1


    Mendeley users who have this article in their library.
  • N/A


    Citations of this article.


© 2014 Elsevier B.V. All rights reserved. The lithium ion conductivities of as-prepared composite membranes consisting of a polyethylene oxide (PEO) matrix with various contents of tetragonal Li 7 La 3 Zr 2 O 12 (LLZO) were evaluated, and the optimum composition (52.5% LLZO) was determined by performing AC impedance measurements. The ionic conductivities of the composite membranes pass through a maximum as the LLZO content varies. Therefore, the hybridization of the organic and inorganic components of these membranes results in synergetic effects on their lithium ionic conductivity. In addition, tests of Li/composite membrane/LiNi 0.6 Co 0.2 Mn 0.2 O 2 half-cells found that their charge/discharge properties are better than those of a PEO-only membrane and a membrane containing 52.5% Al 2 O 3 instead of LLZO.

Author-supplied keywords

  • Hybridization
  • Inorganic solid electrolyte
  • Ionic conductivity
  • Polyethylene oxide
  • Synergetic effect

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


  • J.-H. Choi

  • C.-H. Lee

  • J.-H. Yu

  • C.-H. Doh

  • S.-M. Lee

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free