Evaluation of cytochrome P450 mechanism and kinetics using kinetic deuterium isotope effects

  • Higgins L
  • Bennett G
  • Shimoji M
 et al. 
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Abstract

In this paper two hypotheses are tested:(i) the active oxygen species is similar in energetics for all cytochrome P450 (CYP) enzymes and (ii) linear free-energy relationships can be used to evaluate the mechanism of the reaction of these enzymes. A series of intramolecular ...

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Authors

  • L A Higgins

  • G A Bennett

  • M Shimoji

  • J P Jones

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