Oxygen vacancies are increasingly recognized to play a role in phenomena observed at transition-metal oxide interfaces. Here, we report a study of SrRuO 3 and La 0.7Sr 0.3MnO 3 interfaces using a combination of quantitative aberration-corrected scanning transmission electron microscopy, electron energy-loss spectroscopy, and density functional calculations. Cation displacements are observed at the interface, indicative of a dipolelike electric field even though both materials are nominally metallic. The observed displacements are reproduced by theory if O vacancies are present in the near-interface La 0.7Sr 0.3MnO 3 layers. The results suggest that atomic-scale structural mapping can serve as a quantitative indicator of the presence of O vacancies at interfaces. © 2012 American Physical Society.
CITATION STYLE
Borisevich, A. Y., Lupini, A. R., He, J., Eliseev, E. A., Morozovska, A. N., Svechnikov, G. S., … Pennycook, S. J. (2012). Interface dipole between two metallic oxides caused by localized oxygen vacancies. Physical Review B - Condensed Matter and Materials Physics, 86(14). https://doi.org/10.1103/PhysRevB.86.140102
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