Ionic liquids as green electrolytes for the electrodeposition of nanomaterials

  • El Abedin S
  • Pölleth M
  • Meiss S
 et al. 
  • 60


    Mendeley users who have this article in their library.
  • 114


    Citations of this article.


Ionic liquids, especially air and water stable ones, experience much attention, since they have attractive physical properties. We exemplify in this paper the potential of ionic liquids in the electrodeposition of nanocrystalline metals without additives. The results show that nanocrystalline copper and aluminium can be electrodeposited in the air and water stable ionic liquids 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([BMP]TFO) and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide ([BMP]Tf2N), respectively, on conventional solid electredes with sufficient electronic conductivity. Generally, the obtained A] or Cu deposits are shiny, dense and adherent with very fine crystallites with average sizes of about 30 and 40 nm, respectively. The [BMP](+) cation might act as a grain refiner, leading to nanosized deposits. The results of first attempts to use plasmas as mechanically contact-free electrodes for the cathodic deposition cf nanoscaled metals (glow discharge electrodeposition) are also presented. The relevance of our results for the development of a green process to make nanomaterials as catalysts for fuel processing is briefly discussed.

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


  • S. Zein El Abedin

  • M. Pölleth

  • S. A. Meiss

  • J. Janek

  • F. Endres

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free