Kinetics of L-arabinose oxidation over supported gold catalysts with in situ catalyst electrical potential measurements

  • Kusema B
  • Mikkola J
  • Murzin D
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Abstract

The kinetics of L-arabinose selective oxidation over Au/Al2O3 catalysts
was studied with simultaneous in situ catalyst electrical potential
measurements. An oxidative dehydrogenation mechanism was proposed and a
kinetic model taking into account the catalyst potential changes was
developed. The kinetic model was implemented into the three-phase system
and validated with the experimental observations. The agreement of the
kinetic model to the experimental data, in line with the suggested
reaction mechanism, was satisfactory.

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Authors

  • Bright T Kusema

  • Jyri-Pekka Mikkola

  • Dmitry Yu Murzin

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