Mixed transition-metal oxides: Design, synthesis, and energy-related applications

  • Yuan C
  • Wu H
  • Xie Y
 et al. 
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A promising family of mixed transition-metal oxides (MTMOs) (designated as Ax B3-x O4 ; A, B=Co, Ni, Zn, Mn, Fe, etc.) with stoichiometric or even non-stoichiometric compositions, typically in a spinel structure, has recently attracted increasing research interest worldwide. Benefiting from their remarkable electrochemical properties, these MTMOs will play significant roles for low-cost and environmentally friendly energy storage/conversion technologies. In this Review, we summarize recent research advances in the rational design and efficient synthesis of MTMOs with controlled shapes, sizes, compositions, and micro-/nanostructures, along with their applications as electrode materials for lithium-ion batteries and electrochemical capacitors, and efficient electrocatalysts for the oxygen reduction reaction in metal-air batteries and fuel cells. Some future trends and prospects to further develop advanced MTMOs for next-generation electrochemical energy storage/conversion systems are also presented.

Author-supplied keywords

  • energy storage/conversion
  • lithium-ion batteries
  • mixed metal oxides
  • oxygen reduction
  • supercapacitors

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  • Changzhou Yuan

  • Hao Bin Wu

  • Yi Xie

  • Xiong Wen Lou

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