Ca-43 MAS NMR spectra have been collected for 12 solid phases including silicates, carbonates and sulphates. In all cases Ca-43 was present at natural abundance, the first time such experiments have been reported. In general the lines are broad and featureless, though in the case of calcite a second order quadrupolar lineshape was observed. Within each class of compounds (silicates, carbonates etc.), the isotropic chemical shift appears to be linearly correlated with the mean Ca-O bond length of the first coordination shell of calcium, with a similar gradient for all of the classes of compounds studied. (C) 1997 Elsevier Science B.V.
CITATION STYLE
Dupree, R., Howes, A. P., & Kohn, S. C. (1997). Natural abundance solid state Ca-43 NMR. Chemical Physics Letters, 276, 399–404. Retrieved from http://links.isiglobalnet2.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=mekentosj&SrcApp=Papers&DestLinkType=FullRecord&DestApp=WOS&KeyUT=A1997XZ47800016 papers3://publication/uuid/391F489B-B8BC-40EC-8417-B7CF677F7217
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