We have examined the synthesis of cyclic oligomers with pendant norbornadiene (NBD) moieties based on the calixarenes [p-pert-butylcalix[8]arene (BCA), p-methylcalix[6]arene (MCA), calix[4]resorcinarene (CRA), 2,8,14,20-tetradecylcalix[4]resorcinarene (CRA10), and 2,8,14,20-tetrakis(p-hydroxyphenyl)calix[4]resorcinarene (CRAph)]. The photochemical valence isomerization of the obtained calixarene derivatives containing NBD moieties proceeded very smoothly to afford the corresponding quadricyclane (QC) moieties, and it was found that the large refractive-index changes (Δn's = 0.028-0.061) before and after photo-isomerization.
CITATION STYLE
Kudo, H., Ueda, W., Sejimo, K., Mitani, K., Nishikubo, T., & Anada, T. (2004). New large refractive-index change materials: Synthesis and photochemical valence isomerization of the calixarene derivatives containing norbornadiene moieties. Bulletin of the Chemical Society of Japan, 77(7), 1415–1422. https://doi.org/10.1246/bcsj.77.1415
Mendeley helps you to discover research relevant for your work.