Atmospheric Chemistry and Physics Discussions, vol. 6, issue 5 (2006) pp. 10373-10402
Organic material from the oceans surface can be incorporated into sea salt aerosol particles often produc- ing a surface film on the aerosol. Such an organic coat- ing can reduce the mass transfer between the gas phase and the aerosol phase influencing sea salt chemistry in the ma- rine atmosphere. To investigate these effects and their im- portance for the marine boundary layer (MBL) we used the one-dimensional numerical model MISTRA.We considered the uncertainties regarding the magnitude of uptake reduc- tion, the concentrations of organic compounds in sea salt aerosols and the oxidation rate of the organics to analyse the possible influence of organic surfactants on gas and liquid phase chemistry with a special focus on halogen chemistry. By assuming destruction rates for the organic coating based on laboratory measurements we get a rapid destruction of the organic monolayer within the first meters of the MBL. Larger organic initial concentrations lead to a longer lifetime of the coating but lead also to an unrealistically strong de- crease of O3 concentrations as the organic film is destroyed by reaction with O3. The lifetime of the film is increased by assuming smaller reactive uptake coefficients for O3 or by assuming that a part of the organic surfactants react with OH. With regard to tropospheric chemistry we found that gas phase concentrations for chlorine and bromine species decreased due to the decreased mass transfer between gas phase and aerosol phase. Aqueous phase chlorine concentra- tions also decreased but aqueous phase bromine concentra- tions increased. Differences for gas phase concentrations are in general smaller than for liquid phase concentrations. The effect on gas phase NO2 or NO is very small (reduction less than 5%) whereas liquid phaseNO2 concentrations increased in some cases by nearly 100%. We list suggestions for fur- ther laboratory studies which are needed for improved model studies.
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