(Chemical Equation Presented) 22 Years in the making: Azadirachtin (1) was synthesized for the first time by a highly convergent approach, utilizing a Claisen rearrangement and a radical cyclization as key steps. End-game strategies relied on intermediate 2, which could be obtained by synthetic methods as well as by degradation of 1. Bn = benzyl, TBS = tert- butyldimethylsilyl. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
CITATION STYLE
Veitch, G. E., Beckmann, E., Burke, B. J., Boyer, A., Ayats, C., & Ley, S. V. (2007). A relay route for the synthesis of azadirachtin. Angewandte Chemie - International Edition, 46(40), 7633–7635. https://doi.org/10.1002/anie.200703028
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