Solid-state high-resolution 29Si NMR in zunyite

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Abstract

High-resolution 29Si NMR spectra of zunyite Si5Al13O20 (OH,F)18Cl have been studied by magic-angle sample spinning in combination with high-power proton decouplina and polarization transfer. The isotropic 29Si chemical shift depends mainly on the number of Si-O-Si bridges and the bond angles in these bridges connecting the different SiO4 tetrahedra. © 1983.

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Grimmer, A. R., von Lampe, F., Tarmak, M., & Lippmaa, E. (1983). Solid-state high-resolution 29Si NMR in zunyite. Chemical Physics Letters, 97(2), 185–187. https://doi.org/10.1016/0009-2614(83)85013-1

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