"Supra" crystal: Control of the ordering of self-organization of cobalt nanocrystals at the mesoscopic scale

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Abstract

Cobalt nanocrystals with very low size distribution self-assemble to produce well-grown face-centered cubic (fee) "supra" crystals. By adjusting the substrate temperature during the solvent evaporation process, structural ordering is controlled. Hence, it is possible to obtain either a long-range arrangement of the magnetic nanocrystals or a short-range ordering. The film morphology can be improved in terms of homogeneity and crack density by lowering the evaporation rate of the solvent. The ordering of the nanocrystals into a "supra" crystal is accompanied by a slight change of the magnetic properties.

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Lisiecki, I., Albouy, P. A., & Pileni, M. P. (2004). “Supra” crystal: Control of the ordering of self-organization of cobalt nanocrystals at the mesoscopic scale. Journal of Physical Chemistry B, 108(52), 20050–20055. https://doi.org/10.1021/jp0473725

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