Abstract
Treatment of [Mo(CO)3(NCMe)3] with bis (diphenylphosphino)methane (dppm) and triphenylphosphine (PPh3) at 50 °C afforded mer-[Mo(CO)3(PPh3) (κ2- dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P-1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å , b = 80.8400(10)°, Z = 2 and V = 1959.8(2) Å 3. © Springer Science+Business Media, LLC 2010.
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Ghosh, S., Kabir, S. E., Camellia, F. K., Hossain, M. K., Haworth, D. T., Lindeman, S. V., … Bennett, D. W. (2010). X-ray structure of mer-[Mo(CO)3(PPh3) (κ2-dppm)]. Journal of Chemical Crystallography, 40(8), 712–715. https://doi.org/10.1007/s10870-010-9777-8
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