Abstract
Ni takes a load off: Nickel(0) and a strained alkene react to form a stable tris(alkene) complex, which eliminates the corresponding trans,trans,trans- cyclobutane upon heating. A higher proportion of alkene to Ni0 precursor yielded the first all-alkyl complex of nickel(IV) (see structure; Ni: green). These reactions, which involve ligand coupling, are driven by relief of ring strain in the alkene. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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Carnes, M., Buccella, D., Chen, J. Y. C., Ramirez, A. P., Turro, N. J., Nuckolls, C., & Steigerwald, M. (2009). A stable tetraalkyl complex of nickel(IV). Angewandte Chemie - International Edition, 48(2), 290–294. https://doi.org/10.1002/anie.200804435
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