Palm oil-based polyester polyol is synthesized by ring opening reaction on epoxidized palm olein by phthalic acid. The reaction is carried out in a solvent free and noncatalyzed condition with the optimal reaction condition at 175°C for 5 h reaction time. The physical state of the product is a clear bright yellowish liquid with low viscosity value of 5700-6700 cP at 25°C and pour point of 15°C. The chemical structure and molecular weight of the polyester polyol were characterized by FTIR, 1H-NMR, 13C-NMR, and GPC. The optimal polyol with molecular weight of 36,308 dalton and hydroxyl value of 78.17 mg KOH/g sample was reacted with polymeric 4,4-methylene diphenyl diisocyanate (pMDI) at isocyanate index of 1.3 to produce polyurethane adhesive. The lap shear strength of the polyurethane adhesive showed two times higher than the commercial wood adhesives. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014, 131, 39967. Copyright © 2013 Wiley Periodicals, Inc.
CITATION STYLE
Ang, K. P., Lee, C. S., Cheng, S. F., & Chuah, C. H. (2014). Synthesis of palm oil-based polyester polyol for polyurethane adhesive production. Journal of Applied Polymer Science, 131(6). https://doi.org/10.1002/app.39967
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