A chromium terephthalate-based solid with unusually large pore volumes and surface area

Abstract

We combined targeted chemistry and computational design to create a crystal structure for porous chromium terephthalate,MIL-101,withvery large pore sizes and surface area. Its zeotype cubic structure has a giant cell volume (È702,000 cubic angstroms), a hierarchy of extra-large pore sizes (È30 to 34 angstroms), and a Langmuir surface area for N2 of È5900 T 300 square meters per gram. Beside the usual properties of porous compounds, this solid has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorpo- ration of Keggin polyanions within the cages