Microstructure and exchange coupling of segregated oxide perpendicular recording media

Abstract

The magnetic properties and corresponding microstructure of (Co 80Pt20)x(metal oxide) 1-xperpendicular recording media have been studied as a function of the volume percentage (vol%) of metal oxide sputtering into the magnetic film. The exchange coupling field (Hex) estimated from the coercivity (Hc) and nucleation field (Hn) decreases rapidly between 0-20 vol% of metal oxide. The analytical transmission electron microscope composition analysis of (Co80 Pt20)x (TiO 2)1-x media confirms that the microstructure includes crystalline grain cores in an apparently amorphous oxide matrix. The grain cores comprise only Co and Pt in a nearly constant ratio independent of the vol% of oxide addition. The amorphous matrix contains Co, Ti, and O, but no Pt. The Co concentration is nearly constant in grain boundary and core regions, unlike high-temperature longitudinal recording media wherein Co segregates to form a concentration gradient in the grain core. Perpendicular media thus maintain fairly high anisotropy of the grain core phase, even for very high-oxide concentrations that significantly decrease remanant magnetization (M rt), Hc, and thermal stability (KuV/kT). © 2007 IEEE.