Recent progress in solid oxide and lithium ion conducting electrolytes research

Abstract

Recent material developments of fast solid oxide and lithium ion conductors are reviewed. Special emphasis is placed on the correlation between the composition, structure, and electrical transport properties of perovskite-type, perovskite-related, and other inorganic crystalline materials in terms of the required functional properties for practical applications, such as fuel or hydrolysis cells and batteries. The discussed materials include Sr- and Mg-doped LaGaO3, Ba2In2O5, Bi 4V2O11, RE-doped CeO2, (Li,La,)TiO3, Li3La3La3Nb 2O12 (M=Nb, Ta), and Na super-ionic conductor-type phosphate. Critical problems with regard to the development of practically useful devices are discussed.