Thiocarbonyl Compounds in [4+2] Cycloadditions: Preparative Aspects

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Abstract

[4+2] Cycloadditions of thiobenzophenones 1a and thiofluorenones 2 with cyclic and open-chain dienes gave cycloadducts in high yields. Assignment of the product structure especially the regiochemistry of the cycloadditions involved 1H- and 13C-NMR spectroscopy, and single-crystal structure determination.

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Breu, J., Höcht, P., Rohr, U., Schatz, J., & Sauer, J. (1998). Thiocarbonyl Compounds in [4+2] Cycloadditions: Preparative Aspects. European Journal of Organic Chemistry, (12), 2861–2873. https://doi.org/10.1002/(sici)1099-0690(199812)1998:12<2861::aid-ejoc2861>3.0.co;2-c

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