Abstract
Two trianionic amine triphenolate ligands are introduced and their isopropoxide Ti(IV) complexes synthesized. The two complexes are mononuclear and C3-symmetrical on the NMR timescale. High barriers to inversion (ΔG‡ > 65 KJ mol-1) between the enantiomers of each complex were found. The complex derived from the bulkier tripodal ligand shows a better resistance to hydrolysis. © 2001 Elsevier Science B.V.
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Kol, M., Shamis, M., Goldberg, I., Goldschmidt, Z., Alfi, S., & Hayut-Salant, E. (2001). Titanium(IV) complexes of trianionic amine triphenolate ligands. Inorganic Chemistry Communications, 4(4), 177–179. https://doi.org/10.1016/S1387-7003(01)00157-5
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