High spectral resolution ozone absorption cross-sections – Part 1: Measurements, data analysis and comparison with previous measurements around 293 K

Abstract

In this paper we discuss the methodology of taking broadband relative and absolute measurements of ozone cross-sections including uncertainty budget, experimental set-ups, and methods for data analysis. We report on new ozone absorption cross-section measurements in the solar spectral region using a combination of Fourier transform and echelle spectrometers. The new cross-sections cover the spectral range 213-1100 nm at a spectral resolution of 0.02-0.06 nm in the UV-visible and 0.12-0.24 nm in the IR at eleven temperatures from 193 to 293 K in steps of 10 K. The absolute accuracy is better than three percent for most parts of the spectral region and wavelength calibration accuracy is better than 0.005 nm. The new room temperature cross-section data are compared in detail with previously available literature data. The temperature dependence of our cross-sections is described in a companion paper (Serdyuchenko et al., 2014). © 2014 Author(s).