Fe oxides loaded on carbon cloth by hydrothermal process as an effective and reusable heterogenous Fenton catalyst

Abstract

Iron based heterogeneous Fenton catalysts are attracting much attention for its economic and environmental friendly characteristics. In this study, iron oxides loaded carbon cloth (assigned as Fe@CC) was prepared using hydrothermal hydrolysis of Fe(NO3)3. The specific surface area of Fe@CC determined by N2 adsorption–desorption Brunauer–Emmett–Teller method was up to 1325.5 m2/g, which increased by 81.8% compared with that of native carbon cloth mainly due to the loading of iron oxide. XPS (X-ray photoelectron spectroscopy) spectra confirmed that the iron oxide on the carbon surface included mainly FeOOH. Its heterogeneous Fenton-like activity was determined using Acid Red G as a model substrate for degradation. Fe@CC maintained high and relatively stable activity during 11 tests, and it showed high COD (Chemical Oxygen Demand) removal efficiency and high apparent H2 O2 utilization efficiency. The homogeneous Fenton reaction using the amount of leached Fe(III) suggested that the surficial reaction on Fe@CC was dominant. The stability and the mechanism for gradual decrease of activity during the first 4 tests were also discussed.