Two-dimensional honeycomb network formed by porphyrinatomanganese(III) and μ4-σ-dimerized 7,7,8,8-tetracyano-p-quinodimethane dianion

Abstract

An unprecedented layered (2-D) honeycomb supramolecular structure comprised of μ4-σ-dimerized 7,7,8,8-tetracyano-p-quinodimethane dianion bridging four S = 2 substituted Mn(III)porphyrins as demonstrated with mesotetrakis(2,4,6-trimethylphenyl)porphyrinato has been structural characterized.