Phosphorescent mono-and diiridium(III) complexes cyclometalated by fluorenyl-or phenyl-pyridino ligands with bulky substituents, as prospective OLED dopants

Abstract

The crystal structures of tris[9,9-dihexyl-2-(5-methoxypyridin-2-yl-?N)-9H-fluoren-3-yl-?C 3]iridium pentane monosolvate, [Ir(C31H38NO)3]·C5H12, (I), di-µ2-chlorido-bis{bis[2-(5-fluoropyridin-2-yl)-9,9-dihexyl-9H-fluoren-3-yl]iridium} pentane 0.3-solvate, [Ir2(C30H35FN)4Cl2]·0.3C5H12, (II), di-µ2-cyanato-bis{bis[9,9-dihexyl-2-(5-methoxypyridin-2-yl)-9H-fluoren-1-yl]iridium} pentane monosolvate, [Ir2(C31H38NO)4(NCO)2(NCO)2]·C5H12, (III), and {µ-N,N'-bis[3,5-bis(trifluoromethyl)phenyl]oxamidato}bis(bis{2-[4-(2,4,6-trimethylphenyl)pyridin-2-yl]phenyl-?2 C 1,N'}iridium)-chlorobenzene-pentane (1/2.3/0.4), [Ir2(C20H19N)4(C18H6F12N2O2)]·2.3C6H5Cl·0.4C5H12, (IV), synthesized in the quest for organic light-emitting devices, were determined. The bis-µ2-chloro and bis-µ2-cyanato complexes have and configurations of the distorted octahedral Ir centres in racemic crystals, whereas the oxamido complex has a centrosymmetric (meso) structure with the configuration. The bridging oxamido moiety has a nearly planar anti geometry. All structures show substantial disorder of both host molecules and solvents of crystallization.