Flash Communication: Straightforward Synthesis of a Cp*Co(III) Complex Featuring a Bis-Carbene Ligand: Electrochemical Properties

Abstract

The synthesis of a new Cp*Co(III) complex bearing a bis-carbene ligand (1,1′-dimethyl-4,4′-bi-1,2,4-triazol-5,5′-ylidene, bitz) is reported. The synthetic approach utilizes a Co(I) precursor and a bis-triazolium salt without the need for a base or an external oxidant. The electrochemical properties of the complex have been studied.