16-[(E)-Benzylidene]-13-hydroxy-4-methyl-2-phenyl-4,14-diazapentacyclo-[12. 3.1.01,5.05,13.07,12]octadeca-7(12),8,10- triene-6,17-dione

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Abstract

In the title compound, C30H26N2O 3, the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclopentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The molecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(5) ring motif. Centrosymmetrically related molecules are linked via two pairs of inter-molecular C-H⋯O inter-actions, forming R22(16) ring motifs. In the crystal packing, the molecules are linked into two-dimensional networks parallel to the ab plane via C-H⋯O inter-actions.

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Kumar, R. S., Osman, H., Ali, M. A., Quah, C. K., & Fun, H. K. (2010). 16-[(E)-Benzylidene]-13-hydroxy-4-methyl-2-phenyl-4,14-diazapentacyclo-[12. 3.1.01,5.05,13.07,12]octadeca-7(12),8,10- triene-6,17-dione. Acta Crystallographica Section E: Structure Reports Online, 66(7). https://doi.org/10.1107/S1600536810020271

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