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Pentafluoroethyl-Substituted Sulfonium Ylides: New Electrophilic Pentafluoroethylating Reagents

Chinese Journal of Organic Chemistry (2019) 39(1) 257-264
DOI: 10.6023/cjoc201807018
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Abstract

Two electrophilic pentafluoroethylating reagents of pentafluoroethyl(p-methylphenyl)sulfonium bis(carbometh- oxy)methylide (4a) and pentafluoroethyl(4-nitrophenyl)sulfonium bis(carbomethoxy)methylide (4b), and their reactions under mild conditions with β-ketoesters, aryl iodides and heteroaromatics are described.

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Liu, Y., Ge, H., Lu, L., & Shen, Q. (2019). Pentafluoroethyl-Substituted Sulfonium Ylides: New Electrophilic Pentafluoroethylating Reagents. Chinese Journal of Organic Chemistry, 39(1), 257–264. https://doi.org/10.6023/cjoc201807018

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