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Rotationally state-selected HBR+: Preparation and characterization

Chemical Physics Letters (1989) 159(5-6) 399-405
DOI: 10.1016/0009-2614(89)87507-4
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Abstract

Rotationally state-selected HBr+ ions have been prepared by 2 + 1 resonance-enhanced multiphoton ionization (REMPI) via Rydberg states of HBr, and characterized by laser-induced fluorescence (LIF) using the HBr+ A 2Σ+-X2Π system. The experiment has been conducted under bulb conditions of 10-50 m Torr. The rotationally unrelaxed distribution of HBr+ internal states shows that the ionization step can be highly selective, depending on the intermediate Rydberg state chosen. © 1989.

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Xie, J., & Zare, R. N. (1989). Rotationally state-selected HBR+: Preparation and characterization. Chemical Physics Letters, 159(5–6), 399–405. https://doi.org/10.1016/0009-2614(89)87507-4

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