Formation constants for selected organo—metal (Al 3+ , Fe 3+ )—phosphate complexes

Abstract

The possible formation of organo–metal–phosphate complexes (O–M–P) in aqueous solutions is examined by potentiometric titration analysis. The complex-forming solutions contain Al 3+ -ions or Fe 3+ -ions, organic acids (salicylic, phthalic, oxalic, and citric acids) and phosphate ions. The titrations are done within the precipitation-free pH-region from 2 to 4.5 (approximately) at 25 °C under nitrogen at an ionic strength of 0.2 M KCl. The calibration of the electrode pair (glass-electrode, calomel-reference electrode) and the determination of the formation constants are facilitated by analyzing the pertinent curves with the ACBA-(Arena etal.) and MINIQUAD-(Gans etal.) computer programs. The results suggest (i) that O–M–P complexes are readily formed, and that the power of selected organic acids to form ternary mixed-ligand complexes with Al 3+ -ions and phosphate ions decreases in the order salycilate > citrate > oxalate > phthalate. Also, Fe 3+ -ions are found to be more strongly bound by salicylate and phosphate ions than Al 3+ -ions. The effect of O–M–P formation on the chemical speciation of Al in buffered aqueous solutions containing mineral nutrients for the growth of biological organisms is demonstrated for a special case study.