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Formation of C(sp3)-C(sp3) Bonds by Palladium Catalyzed Cross-Coupling of α-Diazoketones and Allylboronic Acids

Organic Letters (2016) 18(10) 2503-2506
DOI: 10.1021/acs.orglett.6b01132
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Abstract

Palladium catalyzed cross-coupling of allylboronic acids with α-diazoketones was studied. The reaction selectively affords the linear allylic product. The reaction proceeds with formation of a new C(sp3)-C(sp3) bond. The reaction was performed without an external oxidant, likely without the Pd-catalyst undergoing redox reactions.

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Belhomme, M. C., Wang, D., & Szabó, K. J. (2016). Formation of C(sp3)-C(sp3) Bonds by Palladium Catalyzed Cross-Coupling of α-Diazoketones and Allylboronic Acids. Organic Letters, 18(10), 2503–2506. https://doi.org/10.1021/acs.orglett.6b01132

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