XPS study of mechanically activated YBa2Cu3O 6+ δ and NdBa2Cu3O6+ δ

Abstract

Oxides RBa2Cu3O6+δ (R=Y, Nd) subjected to mechanical activation in AGO-2 mill have been studied by X-ray photoelectron spectroscopy (XPS), thermal analysis, and magnetometry. It has been shown that mechanoactivation accelerates chemical degradation under the impact of H2O and CO2 in YBa2Cu 3O6+δ samples. Degradation occurs in the standard way. Investigation of mechanically activated NdBa2Cu 3O6+δ has revealed other results. It has been suggested that CO2 can diffuse into its structure more freely than in YBa2Cu3O6+δ; as a result, carbonization may proceed directly in the volume of NdBa2Cu3O 6+δ and independently of the hydrolysis process. In addition, the mechanism of interaction between the oxide and water is not active and not "traditional" for the homologous series REBa2Cu 3O6+δ (where RE = rare earth and Y) - the characteristic "color" phase (Nd2BaCuO5) is not formed during hydrolysis. It is known that high-temperature treatment of NdBa2Cu3O6+δ oxide results in partial substitution of cations Ba by Nd; which is accompanied by decrease in the superconducting transition temperature and formation of the impurity phase Ba2Cu3O5+y. According to our data, mechanical activation of the resulting solid solution Nd1+xBa 2-xCu3O6+δ unexpectedly has led to the reverse redistribution of cations, which has been manifested in the complete disappearance of the impurity phase and increase in Tc. © 2013 A. V. Fetisov et al.