Oxidation and microstructural behaviors of ni-based alloys strengthened by (Ta, hf)c carbides at 1250◦c in air

Abstract

Two alloys based on nickel and designed to be reinforced by MC carbides thanks to the presence of Hf and Ta were produced by casting. They were subjected to 50 h-long isothermal exposure at 1250◦C in synthetic air with thermogravimetric monitoring of the oxidation progress. In the as-cast state, they contain both significant quantities of (Hf,Ta)C carbides. Their verified melting start temperatures, close to 1300◦C, allowed performing the planned oxidation test. The two alloys demonstrated a chromia-forming behavior with limited mass gain rates. However, they also showed a rather low resistance to oxide spallation at cooling, which is in proportion with the Ta/Hf ratio. After 50 h at 1250◦C, the morphology of the carbides had significantly evolved, from their initial script-like shape to a fragmented and coalesced state. The results are promising, but the use of these alloys at 1250◦C needs further improvements on the mechanical level.