Abstract
A Mannich-insertion strategy was employed in the synthesis of cytostatic 1. The synthesis allowed the absolute and relative stereochemistry to be confirmed and yielded quantities of 1 suitable for upcoming biological testing. Boc = tert-butoxycarbonyl.
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APA
Von Nussbaum, F., & Danishefsky, S. J. (2000). A rapid total synthesis of spirotryprostatin B: Proof of its relative and absolute stereochemistry. Angewandte Chemie - International Edition, 39(12), 2175–2178. https://doi.org/10.1002/1521-3773(20000616)39:12<2175::AID-ANIE2175>3.0.CO;2-J
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