3-[(4-Phenylpiperazin-1-yl)methyl]-5-(thiophen-2-yl)-2,3-dihydro-1,3, 4-oxadiazole-2-thione

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Abstract

In the title compound, C17H18N4OS 2, the 2-thienyl ring is disordered over two co-planar, opposite orientations in a 0.684 (2): 0.316 ratio. The 1,3,4-oxadiazole ring is almost co-planar with the attached 2-thienyl ring [dihedral angles of 5.34 (19) and 4.8 (5)° for the major and minor components, respectively]. The relative disposition of the thione- and ring-S atoms is anti for the major orientation of the 2-thienyl residue. Overall, the shape of the molecule approximates the letter V. In the crystal, a three-dimensional architecture is consolidated by a combination of weak C - H⋯S and C - H⋯π contacts.

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El-Emam, A. A., Al-Omar, M. A., Al-Obaid, A. R. M., Ng, S. W., & Tiekink, E. R. T. (2013). 3-[(4-Phenylpiperazin-1-yl)methyl]-5-(thiophen-2-yl)-2,3-dihydro-1,3, 4-oxadiazole-2-thione. Acta Crystallographica Section E: Structure Reports Online, 69(5). https://doi.org/10.1107/S1600536813009252

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